With the continuous advancement of textile production technology, more and more new fibers have become the raw materials of textiles, which has brought about the problem of identifying fibers for textiles. Commonly used fiber identification methods include microscopic observation, combustion, reagent color development, dyeing, dissolution, etc.
1 Microscopic observation method
Make longitudinal slices and cross-sectional slices of the fibers, observe the longitudinal and transverse morphology of the fibers under a microscope, and identify the fibers based on differences in morphological characteristics, see Table 1.
Table 1 Morphological characteristics of various fibers
Fiber types |
Vertical form |
Cross-sectional shape |
Tencel fiber |
smooth |
More regular round or oval shape, with skin and core layer |
Modal fiber |
There are 1 to 2 grooves in the longitudinal direction |
Irregular, similar to a round waist, smoother, with a skin core |
Soy fiber |
The surface has irregular grooves and island-like concavities |
Flat dumbbell shape and round waist |
Bamboo fiber |
There are grooves on the surface |
Zigzag type, with skin and core layer |
Chitin fiber |
There are obvious grooves on the surface |
The edge is jagged and the core layer has obvious small gaps |
Viscose fiber |
There are grooves on the surface |
Zigzag type, with skin and core layer |
Cotton fiber |
There are natural twists |
The waist is round with a middle cavity |
Silk |
Smooth surface |
Irregular triangle |
Wool fiber |
There are scales on the surface |
Circle |
Polyester fiber |
Rod-shaped |
Smooth round surface |
2 Combustion method
Different fibers have different flames, smoke, odors, residues, etc. during the burning process. Therefore, fiber types can be distinguished according to the characteristics of the fibers during and after burning, as shown in Table 2.
Table 2 Characteristics of various fibers during and after combustion
Fiber types |
Close to the flame |
In flames |
Leave the flame |
Burning smell |
Residue form |
Tencel fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
Gray black gray |
Modal fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
Gray black gray |
Soy protein fiber |
Shrink |
It does not melt when burning, but has black smoke |
Not easy to burn |
Burning hair smell |
Crunchy black ash |
Bamboo fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
Gray black gray |
Chitin fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
Gray black gray |
Viscose fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
A small amount of off-white ash |
Cotton fiber |
Does not melt or shrink |
Burn quickly |
Keep burning |
The smell of burning paper |
A small amount of off-white ash |
Silk |
Shrink |
Gradually burning |
Not easy to burn |
Burning hair smell |
Crunchy black ash |
Wool fiber |
Shrink |
Gradually burning |
Not easy to burn |
Burning hair smell |
Crunchy black ash |
Polyester fiber |
Shrinkage melt |
Melt first and then burn, with solution dripping |
Can spread burning |
Special aroma |
Glassy dark brown hard ball |
3 Reagent color development method
Since the structures of various fibers are different, they have different coloring reactions to iodine and potassium iodide solutions. The fibers can be identified by observing the color and swelling of the fibers after the action of the reagents. This identification only applies to white fibers, and colored fibers must fade before testing can be conducted. Reagent preparation: Dissolve 20 grams of iodine in 100 ml of saturated potassium iodide solution, mix thoroughly, and then soak the fiber for 1 minute. After sufficient washing, judge according to its color, see Table 3.
Table 3 Coloring reactions of various fiber burning to iodine solution
Fiber types |
Tencel fiber |
Modal fiber |
Soy protein fiber |
Bamboo fiber |
Chitin fiber |
Color development in iodine solution |
Black, blue and green |
Blue gray |
Brown |
Blue gray |
Black |
Types of fiber |
Viscose fiber |
Cotton fiber |
Silk |
Wool fiber |
Polyester fiber |
Color development in iodine solution |
Black, blue and green |
No staining |
Light yellow |
Light yellow |
No staining |
4 staining methods
The dyeing method is used to identify fibers, mainly based on the different color reactions of various fibers to dyes. There are two types of dyeing methods: cold dyeing and boiling dyeing. The recipe of the dyeing method is shown in Table 4.
Table 4 Dyeing method formula
Cold dyeing |
Boiling dyeing method |
||
Dyes |
Weight (g) |
Dyes |
Weight (g) |
Direct Indigo 2B |
2.5 |
Acid fuchsin 6B |
1 |
Acid fuchsin 6B |
3 |
Salt base light yellow (thick) |
1 |
Picric acid |
5 |
Disperse blue GF |
0.5 |
Tannin |
5 |
Pancreas plus bleach T |
0.5 |
Pour the formula in Table 4 into 50 ml of ethanol and stir until dissolved, then dilute to 500 ml with distilled water for later use. The cold dyeing method directly puts the fiber into the solution for dyeing, then rinses the fiber with cold water, squeezes out the water, and observes the color for identification; the boiling dyeing method puts the fiber into the solution for dyeing, boils it for 3 minutes, rinses it 3 times, and then puts it into 0.1 % of the pancreas plus bleaching T solution, squeeze out the water, and observe the color for identification. The dyeing reactions of various fibers are shown in Table 5.
Table 5 Dyeing reactions of various fibers
Fiber types |
Cold dyeing method |
Boiling dyeing method |
Cotton fiber |
Purple |
Earthy yellow |
Viscose fiber |
Red purple |
Light yellow |
Vinyl |
Light yellow-green |
Dark olive green |
Acrylic |
No color |
Light yellow |
Polyester |
No color |
Light sky blue |
Nylon |
Light yellow |
Dark grass green |
5 Dissolution method
The dissolution method is an effective method to identify various fibers. The principle is to use the dissolution characteristics of various fibers in different chemical solvents and at different temperatures to determine their varieties. The fibers to be identified can be put into a test tube, inject a certain solvent, stir with a glass rod, and observe the dissolution of the fibers. If the amount of fiber is very small, you can also put the sample into the concave surface with a concave slide, add solvent, cover the slide, and observe directly under the microscope. Using dissolution method to identify fibersAt this time, the concentration of the solvent and the heating temperature should be strictly controlled, and the dissolution speed of the fiber should be paid attention to. Using the dissolution method requires an accurate understanding of the chemical properties of various fibers, and the inspection procedures are also complicated. The microscopic observation method and combustion method are more intuitive, but inspectors must have rich practical experience; the reagent colorimetric method and staining method are more complicated to operate and can be used under special circumstances.
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